Cathodic protection is an electrochemical process which halts the natural reaction (corrosion) of metals in a particular environment by superimposing an electrochemical cell more powerful than the corrosion cell. Sacrificial Anodes are fitted or bonded to the metal to be protected which in turn as it has a greater electrical potential than the anode material becomes cathodic and causes the anode to waste instead of itself. The number and size of anodes is determined by the type of material and the surface area being protected.
The majority of ROV frames are made of aluminium (some TMS's are mild steel, other frames can be Stainless so corrosion is not a problem). If you look at a table which lists the potential differences (voltage) between various metals you always want to choose an anode which is more negative (i.e. more reactive) than the metal you wish to protect.
Doing this, you would expect that zinc is not suitable to protect your aluminium ROV, that you should use Magnesium.
Magnesium is good for protection, however, with pure Magnesium anodes they will have to be replaced on a regular basis, giving a high maintenance cost. It might be worth while looking into an alloy anode (with a higher percentage of Mg) if that's what is required.
If ROVs operated in freshwater then that would be that, however they mainly work in seawater. MGDuff, one of the major anode suppliers in the Uk for ROVs, say that Zinc should be used for seawater. Be careful if you use too many anodes (or Magnesium anodes), as if there is a great potential difference between the anode and the metal being protected corrosion will actually accelerate and the electrical flow does cause noise on CP and Pipetracker systems.
Anodes form a white coating of oxide on the outside, this should be cleaned off occasionally to ensure the anode material stays in good contact with seawater.
Here are a list of some websites that could offer some more help;
MGDuff, manufacturers of Anodes http://www.mgduff.co.uk/leisure-craft/cathodic-protection.html
NACE International—The Corrosion Society - http://www.nace.org
Unilox Industrial Corporation - http://www.unilox.com
Galvotec Alloys, Inc - http://www.galvotec.com/mainset.html
A H Latham Marine - http://www.zincsmart.com
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